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Title: Tetraazacyclotetradecane Species as Models of the Polyazacrown Macrocycles
By (author): Ryszard B Nazarski
ISBN10-13: 1616684879 : 9781616684877
Illustrations: b/w illus
Format: Paperback
Size: 155x230mm
Pages: 80
Weight: .160 Kg.
Published: Nova Science Publishers, Inc (US) - July   2010
List Price: 61.99 Pounds Sterling
Availability: Temporarily Out of Stock, more expected soon 
Subjects: Chemistry
Three aliphatic molecules and their subsequently formed protonated congeners are considered as representatives of the macrocyclic polyamines (azacrowns) and related polyammonium salts. Important methodological aspects of structural investigations on these highly mobile aza-substituted macrorings are taken into account, especially concerning aqueous solutions over a whole pH range. This book examines various issues about ascertaining donating sites and sequences of the protonation, dynamics and conformational preferences of such multidentate polyamino ligands as potential chelators (complexones) are considered.
Table of Contents:
Introduction -- Azacrowns as Multipurpose Ligands or Receptors (Structural Aspects); NMR Spectroscopy of Tetraazacyclotetradecanes & Structurally Similar Polyaza Macrorings; Computational Methods for Azacrown Macrocycles & Related Polyprotonated Species; Polyaza & Other Macrocycles -- Some Current Achievements; Conclusion; References; Index.
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